IODINE COMPOUNDS WITH THE - OTEF5 LIGAND

被引:8
作者
TUROWSKY, L [1 ]
SEPPELT, K [1 ]
机构
[1] FREE UNIV BERLIN,INST ANORGAN & ANALYT CHEM,FABECKSTR 34-36,W-1000 BERLIN 33,GERMANY
来源
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 602卷 / 11期
关键词
D O I
10.1002/zaac.19916020109
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The compounds (C4H5)4N+I(OTeF5)4- and (C4H9)4N+O = I(OTeF5)4- are made from (C4H9)4N+OTeF5- and I(OTeF5)3, I(OTeF5)5, or O = I(OTeF5)3. The crystal structures exhibit a square planar IO4 geometry for I(OTeF5)4- and a pyramidal geometry with double bonded oxygen for O = I(OTeF5)4-. I(OTeF5)3 crystallizes in very thin plates which made a crystallographic investigation impossible. Cl-I(OTeF5)2 shows isolated molecules with a T-shaped iodine coordination and the chlorine atom in an "equatorial" position.
引用
收藏
页码:79 / 87
页数:9
相关论文
共 43 条
  • [1] SECONDARY BONDING .1. CRYSTAL AND MOLECULAR-STRUCTURES OF (C6H5)2 IX (X=CL, BR, OR I)
    ALCOCK, NW
    COUNTRYMAN, RM
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (03): : 217 - 219
  • [2] SECONDARY BONDING .4. CRYSTAL AND MOLECULAR-STRUCTURE OF MU-OXO-BIS[NITRATO(PHENYL)IODINE(III)]
    ALCOCK, NW
    COUNTRYMAN, RM
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1979, (05): : 851 - 853
  • [3] SECONDARY BONDING .5. CRYSTAL AND MOLECULAR-STRUCTURES OF PHENYLIODINE(III) DIACETATE AND BIS-(DICHLOROACETATE)
    ALCOCK, NW
    COUNTRYMAN, RM
    ESPERAS, S
    SAWYER, JF
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1979, (05): : 854 - 860
  • [4] ALCOCK NW, 1973, ADV INORG CHEM RAD, V15, P1
  • [5] CRYSTAL AND MOLECULAR-STRUCTURE AND RAMAN AND I-127 MOSSBAUER-SPECTRA OF IODINE(III) BIS(FLUOROSULFATE) IODIDE, I(OSO2F)2I
    BIRCHALL, T
    DENES, G
    FAGGIANI, R
    FRAMPTON, CS
    GILLESPIE, RJ
    KAPOOR, R
    VEKRIS, JE
    [J]. INORGANIC CHEMISTRY, 1990, 29 (08) : 1527 - 1530
  • [6] BIRCHALL T, 1987, J INORG CHEM, V21, P1068
  • [7] BOSWIJK HK, 1956, ACTA CRYSTALLOGR, V9, P274
  • [8] THE CRYSTAL STRUCTURE OF I2CL6(ICL3)
    BOSWIJK, KH
    WIEBENGA, EH
    [J]. ACTA CRYSTALLOGRAPHICA, 1954, 7 (05): : 417 - 423
  • [9] BURBANK RD, 1974, INORG CHEM, V13, P1071
  • [10] CRYSTAL STRUCTURE OF BETA-IODINE MONOCHLORIDE
    CARPENTER, GB
    RICHARDS, SM
    [J]. ACTA CRYSTALLOGRAPHICA, 1962, 15 (APR): : 360 - &