APPLICABILITY OF HEAT RESISTING ALLOYS TO THE SEPARATOR OF PLANAR TYPE SOLID OXIDE FUEL-CELL

被引:95
作者
KADOWAKI, T [1 ]
SHIOMITSU, T [1 ]
MATSUDA, E [1 ]
NAKAGAWA, H [1 ]
TSUNEIZUMI, H [1 ]
MARUYAMA, T [1 ]
机构
[1] TOKYO INST TECHNOL,DEPT MET ENGN,MEGURO KU,TOKYO 152,JAPAN
关键词
D O I
10.1016/0167-2738(93)90310-Y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Generally metallic materials are much more machinable and have higher capacity for conducting electricity and heat than ceramics. But in a high temperature oxidizing atmosphere, metals are oxidized and lose their conductivity. The usability of heat resisting alloys as solid oxide fuel cell (SOFC) separators was evaluated, and the effects of the electrical conductive oxide coating onto the alloys on the oxidation resistance and the electrical conductivity was tested. Cr2O3-forming alloys which were coated with La0.85Sr0.15CoO3 exhibited electrical resistance as low as 5 m Omega cm(2) for 8000 h at 1273 K in air. A fuel cell with the coated alloy separator generated 0.73 V at 300 mA/cm(2).
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页码:65 / 69
页数:5
相关论文
共 18 条
  • [1] BAUER AA, 1974, 1930 BATT MEM I REPT
  • [2] DOKIYA M, 1989, INTERSOC ENERGY CONV, V24, P1547
  • [3] DOKIYA M, 1990, MOL JAPAN, V28, P83
  • [4] DOKIYA M, 1990, FINE CERAMICS, V11, P21
  • [5] FRIAUF RJ, 1972, PHYSICS ELECTROLYTES, V1
  • [6] OXIDATION OF NI-CR-AL ALLOYS BETWEEN 1000 DEGREES AND 1200 DEGREES C
    GIGGINS, CS
    PETTIT, FS
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1971, 118 (11) : 1782 - &
  • [7] HAGEL WC, 1963, T AM MET, V56, P586
  • [8] Isenberg A., 1982, NAT FUEL CELL SEM CO, P154
  • [9] IWATA T, 1992, P IFCC, P289
  • [10] KHANDKAR A, 1990, DENKI KAGAKU, V58