ELECTROTHERMAL ATOMIC-ABSORPTION SPECTROMETRIC DETERMINATION OF METALLIC IMPURITIES IN PLATINUM AND PALLADIUM

被引:13
作者
ARPADJAN, S [1 ]
KARADJOVA, I [1 ]
TSEROVSKY, E [1 ]
ANEVA, Z [1 ]
机构
[1] REFINERY & PETROCHEM RES INST,BU-104 BURGAS,BULGARIA
关键词
Atomic absorption spectrometry; Electrothermal atomisation; Palladium; Platinum; Trace impurities;
D O I
10.1039/ja9900500195
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The possibility of using electrothermal atomic absorption spectrometry (ETAAS) for the determination of trace amounts of Ag, Cd, Co, Fe, Ir, Ni, Mn, Pb, Rh and Ru in pure Pt and Pd is investigated. The influence of the matrix elements, Pt and Pd, on the atomisation of the analytes is studied, using various types of graphite tubes and L'vov platform. The optimum conditions for atomisation of the trace elements from the matrix are discussed. A possible mechanism for the atomisation of the elements in the presence of Pd and Pt is proposed.
引用
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页码:195 / 198
页数:4
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