SUBSTITUTION OF INTERLAMELLAR WATER IN VANADIUM PENTOXIDE XEROGEL WITH PROPYLENE CARBONATE AND ITS EFFECTS ON THE CATHODE BEHAVIOR IN A LITHIUM CELL

被引：5

作者：

MIURA, T ^{[1
]}

TAKEHARA, C ^{[1
]}

KISHI, T ^{[1
]}

机构：

[1] KEIO UNIV,FAC SCI & TECHNOL,DEPT APPL CHEM,KOUHOKU KU,YOKOHAMA,KANAGAWA 223,JAPAN

来源：

DENKI KAGAKU | 1991年 / 59卷 / 02期

关键词：

VANADIUM PENTOXIDE XEROGEL; INTERLAMELLAR WATER; LITHIUM SECONDARY CELL;

D O I：

10.5796/kogyobutsurikagaku.59.149

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A modified sort of vanadium pentoxide xerogel with a typical formula of V2O5.0.1H2O.0.3PC was prepared, whose discharge/charge characteristics were investigated in a LiClO4-propylene carbonate (PC) solution. The interlayer gap decreased from 2.2 nm to 1.1 nm after small amount of lithium insertion (Li/V = ca. 0.01). This PC-modified xerogel film cathode as well as V2O5.1.9H2O in a previous work showed incomplete rechargeability in a lithium cell.

引用

页码：149 / 151

页数：3

共 8 条

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