SYNTHESIS OF ENANTIOMERICALLY PURE BICYCLO[3.1.0]HEXANES FROM D-RIBOSE BY INTRAMOLECULAR CYCLOPROPANATION

被引：43

作者：

GALLOS, JK

KOFTIS, TV

KOUMBIS, AE

机构：

[1] Department of Chemistry, Aristotelian University of Thessaloniki

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 06期

关键词：

D O I：

10.1039/p19940000611

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Highly functionalized optically pure bicyclo[3.1.0]hexan-2-ones 6a and 6b are easily obtained by the intramolecular cyclopropanation of a D-ribose derivative using the iodonium ylide or diazo compound methods, which afford the final products with opposite diastereoselectivities.

引用

页码：611 / 612

页数：2

共 39 条

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