KINETICS OF FREE-RADICAL POLYMERIZATIONS IN REACTIVE POLYMER PROCESSING

被引：47

作者：

HUANG, YJ ^{[1
]}

LEE, LJ ^{[1
]}

机构：

[1] OHIO STATE UNIV, DEPT CHEM ENGN, COLUMBUS, OH 43210 USA

来源：

AICHE JOURNAL | 1985年 / 31卷 / 10期

关键词：

PLASTICS - Molding - PLASTICS SHEETS - Sheet Molding Compounds - POLYMERS - Processing - STYRENE - Polymerization;

D O I：

10.1002/aic.690311002

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A kinetic model has been developed for radical chain growth type of reactive polymer processing operations. This model incorporates considerations of the molecular diffusion that is described by a free volume theory and the basic reaction mechanism of the free-radical chain polymerization. Experimental results from the bulk styrene polymerization and a reaction of sheet molding compound (SMC) showed good agreement with the model.

引用

页码：1585 / 1593

页数：9

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