EFFECT OF PH IN THE PD-CATALYZED OXIDATION OF D-GLUCOSE TO D-GLUCONIC ACID

被引：33

作者：

ABBADI, A ^{[1
]}

MAKKEE, M ^{[1
]}

VISSCHER, W ^{[1
]}

VANVEEN, JAR ^{[1
]}

VANBEKKUM, H ^{[1
]}

机构：

[1] EINDHOVEN UNIV TECHNOL,INORGAN CHEM & CATALYSIS LAB,5600 MB EINDHOVEN,NETHERLANDS

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 1993年 / 12卷 / 4-5期

关键词：

D O I：

10.1080/07328309308019408

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The pH effect on the Pd-catalyzed oxidation of glucose to gluconic acid was studied. The oxidation reactions were performed in the pH range 2 to 9 in a batch reactor using Pd/C or Pd black as the catalysts and monitoring the behaviour of the catalyst during the oxidation reaction. The Pd-glucose system was also studied by cyclic voltammetry. It is concluded that gluconic acid in its free form reversibly inhibits the oxidation process in acidic media.

引用

页码：573 / 587

页数：15

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