THE BINARY REAGENT PHI(OAC)(2)-MG(CLO4)(2) - A SET INDUCED RING ENLARGEMENT OF FURAN-DERIVATIVES INTO PYRANONES

被引：34

作者：

DEMICO, A

MARGARITA, R

PIANCATELLI, G

机构：

[1] Centro CNR di Studio per la Chimica delle Sostanze Organiche Naturali, Dipartimento di Chimica, Università La Sapienza, 00185 Roma

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 20期

关键词：

D O I：

10.1016/0040-4039(95)91393-K

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The binary reagent PhI(OAc)(2)-Mg(ClO4)(2) is very efficient for a high conversion of(2-furyl)-1-alcohols into pyranones. The reaction mechanism can be explained in terms of a SET process, with the generation of a cation radical as key intermediate

引用

页码：3553 / 3556

页数：4