NAD(P)H-NAD(P)+ MODELS .73. STRUCTURE-STEREOCHEMISTRY RELATIONSHIP IN THE REACTION OF NAD ANALOG

被引:19
作者
OHNO, A [1 ]
MIKATA, Y [1 ]
GOTO, M [1 ]
KASHIWAGI, T [1 ]
TANAKA, T [1 ]
SAWADA, M [1 ]
机构
[1] OSAKA UNIV, INST SCI & IND RES, CTR MAT ANAL, IBARAKI, OSAKA 567, JAPAN
关键词
D O I
10.1246/bcsj.64.81
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Four different NAD(P)H analogs have been oxidized by various substituted and unsubstituted 1,4-benzoquinones in the presence or absence of magnesium ion. The stereospecificity of the reaction depends not only on the reactivity of quinone but also on that of the analogs as well as on the presence or absence of magnesium ion. The results are discussed from the viewpoint of reaction mechanism for the transfer of a (net) hydride ion.
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页码:81 / 86
页数:6
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