THE SYNTHESIS OF SOLUBLE, SUBSTITUTED SILANE HIGH POLYMERS BY WURTZ COUPLING TECHNIQUES

被引：74

作者：

MILLER, RD ^{[1
]}

THOMPSON, D ^{[1
]}

SOORIYAKUMARAN, R ^{[1
]}

FICKES, GN ^{[1
]}

机构：

[1] UNIV NEVADA,DEPT CHEM,RENO,NV 89557

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1991年 / 29卷 / 06期

关键词：

D O I：

10.1002/pola.1991.080290604

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The Wurtz-type coupling of a number of representative classes of substituted dichlorosilane monomers was investigated in considerable detail. Low temperature polymerization techniques, including ultrasonic activation, were also studied. Similarly, the effect of dipolar additives on the polymerization process was examined. The conclusions drawn from these studies provide some insight into the selection of useful polymerization conditions for the conversion of various monomer types into linear high polymers.

引用

页码：813 / 824

页数：12

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