ON THE MATHEMATICAL-MODEL OF FLOW-INJECTION ANALYSIS .2. THE 2ND-ORDER CHEMICAL-REACTION IN A STRAIGHT TUBE

被引:3
作者
ANDREEV, VP
KONDRATIEVA, TV
机构
[1] Institute for Analytical Instrumentation, Academy of Sciences, 198103 St. Petersburg, 26, pr. Ogorodnikova
关键词
D O I
10.1016/0039-9140(94)00164-2
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The mathematical model of flow injection analysis (FIA) for fast second-order chemical reaction in a straight tube is presented. The sample and reagent are initially premixed and the analytical solution for the detection output, i.e. the integral of the product of reaction concentration over the tube cross-section is given. The optimization of FIA is discussed. It is proposed to put the detector in the real FIA systems immediately after the point where the sample and reagent are satisfactorily mixed.
引用
收藏
页码:1755 / 1763
页数:9
相关论文
共 8 条
[1]   MATHEMATICAL-MODEL OF FLOW-INJECTION ANALYSIS - 1ST-ORDER CHEMICAL-REACTION IN A STRAIGHT TUBE [J].
ANDREEV, VP ;
KHIDEKEL, MI .
ANALYTICA CHIMICA ACTA, 1993, 278 (02) :307-316
[2]  
GROWE CD, 1987, ANAL CHIM ACTA, V194, P49
[3]  
KALOUS V, 1980, BIOFYZIKALNI CHEM, P391
[4]  
NAYFEH AH, 1981, INTRO PERTURBATION T, P117
[5]  
PRIEVE DC, 1982, SEPAR SCI TECHNOL, V17, P1587
[6]  
Ruzicka J., 1981, FLOW INJECTION ANAL
[7]   DISPERSION OF SOLUBLE MATTER IN SOLVENT FLOWING SLOWLY THROUGH A TUBE [J].
TAYLOR, G .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1953, 219 (1137) :186-203
[8]   SAMPLE DISPERSION WITH CHEMICAL-REACTION IN A FLOW-INJECTION SYSTEM [J].
WADA, H ;
HIRAOKA, S ;
YUCHI, A ;
NAKAGAWA, G .
ANALYTICA CHIMICA ACTA, 1986, 179 :181-188