CUX(3)LI(2)-CATALYZED CONJUGATE ADDITION OF DIALKYLMAGNESIUM REAGENTS TO ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS

被引：18

作者：

REETZ, MT

KINDLER, A

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 21期

关键词：

D O I：

10.1039/c39940002509

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper salts of the type CuX(3)Li(2)(X = halogen) catalyse the conjugate addition of dialkylmagnesium compounds to alpha,beta-unsaturated carbonyl compounds in the presence or absence of Me(3)SiCl as an additive, the organomagnesium compounds being prepared from alpha-olefins, hydrogen and magnesium according to the procedure of Bogdanovic.

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页码：2509 / 2510

页数：2

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