CARBON-MONOXIDE AS A BUILDING BLOCK FOR ORGANIC-SYNTHESIS .1. HIGHLY REGIOSELECTIVE ALKOXYCARBONYLATION OF ALLYLBENZENE CATALYZED BY PALLADIUM COMPLEXES

被引：18

作者：

CIPRES, I ^{[1
]}

JENCK, J ^{[1
]}

KALCK, P ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM TOULOUSE,CHIM PROCEDES LAB,EQUIPE CATALYSE & CHIM FINE,118 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1990年 / 58卷 / 03期

关键词：

D O I：

10.1016/0304-5102(90)85028-G

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The various parameters governing the alkoxycarbonylation of 3-phenylpropene were investigated in order to select an efficient catalytic system for the conversion of various naturally-occurring allylbenzenes into the corresponding esters. The complex PdCl2(PPh3)2, in the presence of a slight excess of phosphine and SnCl2·2H2O catalyzed this reaction at 4 MPa, with a good selectivity and a regioselectivity in linear ester as high as 95%. Several diphosphine ligands were conveniently used, and in many cases the regioselectivity was controlled by the reaction conditions. © 1990.

引用

页码：387 / 392

页数：6

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