ON THE PRODUCT VIBRATIONAL DISTRIBUTION OF EXOERGIC REACTIONS - THE B+OH SYSTEM

被引：7

作者：

AGUILAR, A ^{[1
]}

ALBERTI, M ^{[1
]}

GIMENEZ, X ^{[1
]}

GRANDE, X ^{[1
]}

LAGANA, A ^{[1
]}

机构：

[1] UNIV PERUGIA,DIPARTIMENTO CHIM,I-06100 PERUGIA,ITALY

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 233卷 / 03期

关键词：

D O I：

10.1016/0009-2614(94)01454-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The dependence on the collision energy of the product vibrational distribution of exoergic reactions has been investigated by carrying out model and coupled channel calculations for the B + OH --> BO + H process. The location and number of peaks of the three-dimensional results differ from those obtained from collinear and model calculations and agree better with available experimental information. A rationale for this is discussed in terms of the selective product vibrational excitation associated with different orbital angular momentum values.

引用

页码：201 / 206

页数：6

共 38 条

[1]

AGUILAR A, 1993, J CHEM PHYS, V97, P8578

[2]

ALBERTI M, 1988, J MOL STRUC-THEOCHEM, V166, P301

[3] WEAK AND STRONG INTERACTIONS IN CHEMICAL-REACTIONS [J].

BAER, M .

JOURNAL OF CHEMICAL PHYSICS, 1975, 62 (11) :4545-4550

[4] ISOTOPIC REACTIVE SYSTEMS H+CL2 AND D+CL2 - QUANTUM-MECHANICAL TREATMENT OF COLLINEAR ARRANGEMENT [J].

BAER, M .

JOURNAL OF CHEMICAL PHYSICS, 1974, 60 (03) :1057-1064

[5]

BAER M, 1981, J PHYS CHEM-US, V85, P3874

[6] THE EFFECT OF REAGENT TRANSLATIONAL EXCITATION ON THE DYNAMICS OF THE REACTION H+CL-2-]HCL(V',J')+CL [J].

BERG, PA ;

SLOAN, JJ .

JOURNAL OF CHEMICAL PHYSICS, 1994, 100 (02) :1075-1084

[7] PNO-CL AND CEPA INVESTIGATION OF UNSTABLE BORON-NITROGEN AND BORON-OXYGEN COMPOUNDS [J].

BOTSCHWINA, P .

CHEMICAL PHYSICS, 1978, 28 (1-2) :231-241

[8] SUDDEN ROTATION REACTIVE SCATTERING - THEORY AND APPLICATION TO 3-D H+H-2 [J].

BOWMAN, JM ;

LEE, KT .

JOURNAL OF CHEMICAL PHYSICS, 1980, 72 (09) :5071-5088

[9] NEW QUANTUM-DYNAMICAL APPROXIMATION FOR LIGHT-HEAVY-LIGHT CHEMICAL-REACTIONS IN 3 DIMENSIONS THEORY [J].

CLARY, DC .

MOLECULAR PHYSICS, 1981, 44 (05) :1067-1081

[10]

CLARY DC, 1986, THEORY CHEM REACTION, P331

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