SELF-QUENCHING REACTION OF (PHENOXYMETHYL)CHLOROCARBENE WITH DIAZIRINE

被引：6

作者：

LIU, MTH ^{[1
]}

CHATEAUNEUF, JE ^{[1
]}

机构：

[1] UNIV NOTRE DAME,RADIAT LAB,NOTRE DAME,IN 46556

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 1994年 / 20卷 / 02期

关键词：

D O I：

10.1163/156856794X00199

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of laser flash photolysis and product analysis demonstrates that even though (phenoxymethyl)chlorocarbene reacts with its diazirine precursor with a substantial rate constant of 3.5 x 10(8) M(-1)s(-1), the predicted azine product is not formed. These results indicate either carbene/diazirine reversibility or subsequent hydrogen migration of the carbene/diazirine adduct. Also, a rate constant of 2.0 x 10(7) s(-1) for the 12-hydrogen atom migration in (p-nitrophenoxymethyl)chlorocarbene has been determined using the pyridinium ylide technique.

引用

页码：195 / 199

页数：5

共 7 条

[1] ACTIVATION-ENERGY FOR A 1,2-HYDROGEN SHIFT IN (PHENOXYMETHYL)CHLOROCARBENE [J].