SPECTROSCOPIC STUDIES ON THE REACTION OF 1,4,8,11-TETRAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE

被引：22

作者：

NOUR, EM

SHAHADA, LA

SADEEK, SA

TELEB, SM

机构：

[1] Department of Chemistry, Faculty of Science, Zagazig University, Zagazig

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1995年 / 51卷 / 03期

关键词：

D O I：

10.1016/0584-8539(94)E0106-K

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The interaction of iodine with the nitrogen cyclic base 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane (TMTACTD) is studied spectrophotometrically in CHCl3 and the resonance Raman spectrum of the solid product is recorded. The results indicate the formation of the polyiodide species with the formula [(TMTACTD)I](+). I-9(-). The resonance Raman spectrum of the product suggests that the enneaiodide, I-9(-), does indeed contain the I-5(-) unit and this implies that I-9(-) exists as (I-5(-)) (2I(2)) where the I-5(-) portion has a bent configuration with C-2v symmetry. All bond vibrations for the I-5(-) and I-2 units are observed and assigned.

引用

收藏

页码：471 / 474

页数：4

相关论文

共 15 条

[1]

[Anonymous], 1985, PRINCIPLE INSTRUMENT

[2] PREPARATION AND INFRARED-SPECTRA OF HEXAMETHYLENETETRAMINE-DI-IODINE (1-1, 1-2, AND 1-3) [J].

BOWMAKER, GA ;

KNAPPSTEIN, RJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (20) :1928-1931

[3] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDY OF HIGHLY CONDUCTIVE IODINE-DOPED POLYACETYLENE [J].

IKEMOTO, I ;

SAKAIRI, M ;

TSUTSUMI, T ;

KURODA, H ;

HARADA, I ;

TASUMI, M ;

SHIRAKAWA, H ;

IKEDA, S .

CHEMISTRY LETTERS, 1979, (10) :1189-1192

[4] MOLECULAR-COMPLEX OF IODINE WITH 2,3'-BIPYRIDYL [J].

KATO, K ;

YOSHIO, N ;

AIDA, K .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1984, 40 (04) :373-378

[5] UV-LASER EXCITED RESONANCE RAMAN SPECTRUM OF I-/3 ION [J].

KIEFER, W ;

BERNSTEIN, HJ .

CHEMICAL PHYSICS LETTERS, 1972, 16 (01) :5-+

[6] MOLECULAR-COMPLEXES OF IODINE WITH METAL ACETYLACETONATES [J].

KULEVSKY, N ;

BUTAMINA, KN .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1990, 46 (01) :79-83

[7] INFRARED AND RAMAN SPECTRA OF SOME TRIHALIDE IONS - ICL2- IBR2- 13- 12BR- AND BRICL- [J].

MAKI, AG ;

FORNERIS, R .

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1967, A 23 (04) :867-&

[8] SELECTIVE RESONANT RAMAN ENHANCEMENT IN POLYIODIDE CHAINS [J].

MULAZZI, E ;

POLLINI, I ;

PISERI, L ;

TUBINO, R .

PHYSICAL REVIEW B, 1981, 24 (06) :3555-3563

[9] HIGHLY CONDUCTING LINEAR STACKED POLYMERS - IODINE-DOPED FLUOROALUMINUM AND FLUOROGALLIUM PHTHALOCYANINES [J].

NOHR, RS ;

KUZNESOF, PM ;

WYNNE, KJ ;

KENNEY, ME ;

SIEBENMAN, PG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (15) :4371-4377

[10] SPECTROSCOPIC STUDIES OF THE REACTION OF IODINE WITH THE MIXED OXYGEN-NITROGEN CYCLIC BASE 1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE [J].

NOUR, E .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1991, 47 (06) :743-747