RAPID AND STEREOSELECTIVE CONSTRUCTION OF DIENEDIYNES RELATED TO THE NEOCARZINOSTATIN CHROMOPHORE

被引：43

作者：

BRUCKNER, R ^{[1
]}

SCHEUPLEIN, SW ^{[1
]}

SUFFERT, J ^{[1
]}

机构：

[1] EHICS,STEREOCHIM ORGANOMETALL LAB,F-67008 STRASBOURG,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 11期

关键词：

D O I：

10.1016/0040-4039(91)80355-A

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Formylcyclopentanone was transformed into Z configuration dienediynes 15 in three steps. As the key step served Pd catalyzed stereoselective couplings of the isomerically pure bis(enoltriflate) 13 with two equiv. of alkyne.

引用

页码：1449 / 1452

页数：4

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