HOW NUCLEOPHILIC ARE SILYL ENOL ETHERS - KINETICS OF THE REACTIONS OF ELECTRON-RICH CC-DOUBLE BONDED SYSTEMS WITH CARBENIUM IONS

被引：22

作者：

PATZ, M ^{[1
]}

MAYR, H ^{[1
]}

机构：

[1] TH DARMSTADT,INST ORGAN CHEM,PETERSENSTR 22,W-6100 DARMSTADT,GERMANY

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 21期

关键词：

D O I：

10.1016/S0040-4039(00)79164-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rate constants for the reactions of the bis(p-dimethylaminophenyl)carbenium ion 1 with silyl enol ethers, allyl silanes, and allyl stannanes show the reactivity order H2C=CR-CH2SiMe3 < H2C=CR-OSiMe3 < H2C=CR-CH2SnBu3.

引用

页码：3393 / 3396

页数：4

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