MOLECULAR RECOGNITION AND THE DESIGN OF SOLID-STATE STRUCTURES - PROTONATION-INDUCED CONFORMATIONAL CHANGE AND SELF-ASSEMBLY OF 2,6-DIAMIDOPYRIDINIUM PHOSPHATES

被引:62
作者
GEIB, SJ [1 ]
HIRST, SC [1 ]
VICENT, C [1 ]
HAMILTON, AD [1 ]
机构
[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260
关键词
D O I
10.1039/c39910001283
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Protonation of 2,6-diamidopyridine with diaryl phosphates leads to a conformational change in the pyridine from inwardly to outwardly directed amide-NH groups and a resultant self-assembly of the anion and cation into an alternating cocrystal with a novel hydrogen bonding motif.
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页码:1283 / 1285
页数:3
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