STUDIES ON THE EFFICIENT SYNTHESIS OF POLY(PHENYLENEVINYLENE) (PPV) AND POLY(DIMETHOXY PHENYLENEVINYLENE) (DIMETHOXY-PPV)

被引：51

作者：

BURN, PL ^{[1
]}

BRADLEY, DDC ^{[1
]}

BROWN, AR ^{[1
]}

FRIEND, RH ^{[1
]}

HOLMES, AB ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CAVENDISH LAB,CAMBRIDGE CB3 0HE,ENGLAND

来源：

SYNTHETIC METALS | 1991年 / 41卷 / 1-2期

关键词：

D O I：

10.1016/0379-6779(91)91056-G

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The syntheses of poly(phenylene vinylene) (PPV) and poly(2,5-dimethoxy-phenylene vinylene) (dimethoxy-PPV) have been investigated. Precursor polymers which were soluble and processible were prepared and converted to the conjugated polymers. It was found that the conditions needed to prepare precursor polymers were sensitive to the substrate and the conditions required to form the conjugated polymers were dependent on the leaving group present. The spectroscopic and structural properties of the conjugated polymers were found to be determined by the precursor polymer route followed.

引用

页码：261 / 264

页数：4

共 5 条

[1]

CAPISTRAN JD, 1984, ACS POLYM PREPRINTS, V25, P282

[2] PREPARATION OF POLY(PHENYLENE VINYLENE) FROM CYCLOALKYLENE SULFONIUM SALT MONOMERS AND POLYMERS [J].