ELECTROCHEMICAL AND SPECTRAL CHARACTERIZATION OF THE SQUARE SCHEME FOR THE SUBSTITUTION OF N-METHYLPYRAZINIUM CATION ON THE ETHYLENEDIAMINETETRAACETATE COMPLEXES OF RUTHENIUM(III) AND RUTHENIUM(II)

被引：14

作者：

ARAKI, K ^{[1
]}

SHU, CF ^{[1
]}

ANSON, FC ^{[1
]}

机构：

[1] CALTECH,ARTHUR AMOS NOYES LAB CHEM PHYS,DIV CHEM & CHEM ENGN,PASADENA,CA 91125

来源：

INORGANIC CHEMISTRY | 1991年 / 30卷 / 15期

关键词：

D O I：

10.1021/ic00015a020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The large difference in the affinity of N-methylpyrazinium cations for the ethylenediaminetetraacetate complexes of Ru(II) and Ru(III) produces a pattern of irreversibility in the electrochemical responses exhibited by these complexes. A combination of electrochemical and spectral measurements was utilized to obtain estimates of the equilibrium constants, rate constants, and formal potentials for a "square scheme", which characterizes the behavior or the system.

引用

页码：3043 / 3047

页数：5

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