POLYSILANE SYNTHESIS BY CATALYTIC DISPROPORTIONATION OF ALKOXYDISILANES

被引：7

作者：

KABETA, K ^{[1
]}

WAKAMATSU, S ^{[1
]}

IMAI, T ^{[1
]}

机构：

[1] TOSHIBA SILICONE CO LTD, CTR RES & DEV, OHTA, GUNMA 373, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 05期

关键词：

D O I：

10.1246/cl.1994.835

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Network polysilanes with methyl, phenyl, and ethoxy groups (Mw 530 - 7000) were prepared by a catalytic disproportionation reaction of methylethoxydisilanes in the presence of phenylethoxysilanes. Hexyl or cyclohexyl groups were also incorporated into polysilanes when corresponding alkoxysilanes were employed. Reaction of pentamethylethoxydisilane clarified a mechanism of the reaction.

引用

页码：835 / 838

页数：4

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