REARRANGEMENT OF ALLYLIC SULFOXIMINES TO ALLYLIC SULFINAMIDES

被引：23

作者：

GAIS, HJ

SCOMMODA, M

LENZ, D

机构：

[1] Institut für Organische Chemie der RWTH Aachen, 52056 Aachen

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 40期

关键词：

D O I：

10.1016/0040-4039(94)85314-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Thermolysis of the enantiomerically pure allylic sulfoximines 3a,b leads to their partial rearrangement to the isomeric allylic sulfinamides 5a,b and 6a,b, respectively, with complete retention of configuration at the S-atom. Racemization of the allylic sulfoximines 3a,b at the S-atom does not occur.

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页码：7361 / 7364

页数：4

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