UTILITY OF GLYCOSYL PHOSPHITES AS GLYCOSYL DONORS - FRUCTOFURANOSYL AND 2-DEOXYHEXOPYRANOSYL PHOSPHITES IN GLYCOSIDE BOND FORMATION

被引：71

作者：

MULLER, T

SCHNEIDER, R

SCHMIDT, RR

机构：

[1] Fakultät Chemie, Universität Konstanz, D-78434 Konstanz

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 27期

关键词：

D O I：

10.1016/S0040-4039(00)76961-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The discussion of the ease of generating glycosyl donor properties in the important sugar categories (aldoses, ketoses, deoxy sugars, sugar uronates, and 3-deoxy-2-glyculosonates) implies that phosphites of ketoses and deoxy sugars, respectively, should be valuable donors. This is exhibited for fructofuranosyl phosphite 2 and for 2-deoxyhexopyranosyl phosphites 14a,b which are readily available and generally provide disaccharides in high yields.

引用

页码：4763 / 4766

页数：4

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