7-COORDINATE MOLYBDENUM-TIN COMPLEXES CONTAINING PHOSPHORODITHIOATO AND PHOSPHONIODITHIOFORMATE - X-RAY STRUCTURE OF [MO(CO)(2)(S2P(OET)(2))(S(2)CPCY(3))(SNPHCL(2))]CENTER-DOT-CH2CL2

被引：10

作者：

BARRADO, G

MIGUEL, D

PEREZMARTINEZ, JA

RIERA, V

GARCIAGRANDA, S

机构：

[1] UNIV OVIEDO,DEPT QUIM ORGANOMET,E-33071 OVIEDO,SPAIN

[2] UNIV OVIEDO,DEPT QUIM FIS & ANALIT,E-33071 OVIEDO,SPAIN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 466卷 / 1-2期

关键词：

MOLYBDENUM; TIN; DITHIOPHOSPHATE; DITHIOFORMATE;

D O I：

10.1016/0022-328X(94)88040-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of [Mo(CO)(3)(NCMe)(S(2)PX(2))(SnRCl(2))] (1) with an excess of S(2)CPR(3) afford complexes [Mo(CO)(2)(S(2)PX(2))(S(2)CPR(3)')(SnRCl(2))] (2; R = Ph or Bu; X = Oft or Ph; R' = Cy or Pr-i). An X-ray structure analysis of [Mo(CO)(2){S2P(OEt)(2)}(S(2)CPCy(3))(SnPhCl(2))] (3a) showed that both sulphur ligands chelate molybdenum. Additionally, one sulphur atom of the S(2)CPR(3) group is within bonding distance of the tin atom, and thus bridges molybdenum and tin.

引用

页码：147 / 151

页数：5

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