INFRARED STUDY OF SOLIDS AND CAST FILMS OF LONG-CHAIN FATTY-ACIDS

被引：9

作者：

HIGASHI, A

CZARNECKI, MA

OZAKI, Y

机构：

[1] KWANSEI GAKUIN UNIV,DEPT CHEM,NISHINOMIYA,HYOGO 662,JAPAN

[2] WROCLAW UNIV,INST CHEM,PL-50383 WROCLAW,POLAND

来源：

THIN SOLID FILMS | 1993年 / 230卷 / 02期

关键词：

D O I：

10.1016/0040-6090(93)90516-R

中图分类号：

T [工业技术];

学科分类号：

08 [工学];

摘要：

Infrared spectra have been measured for five long-chain fatty acids (CH3(CH2)n COOH; n = 14-18) in solid states, KBr discs and cast films. The acids with even- and odd-numbered carbon atoms show structural differences, not only in the solid states but also in the cast films. For example, the molecular orientation of the hydrocarbon chains and the directions of a and b axes of the orthorhombic subcell in the cast films on Au-evaporated glass slides are different in the even-numbered and the odd-numbered acids.

引用

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页码：203 / 208

页数：6

相关论文

共 33 条

[1]

CHAPMAN D, 1965, STRUCTURE LIPIDS

[2]

INFRARED DETERMINATION OF ORIENTATION OF MOLECULES IN STEARAMIDE MONOLAYERS [J].

CHOLLET, PA ;

MESSIER, J ;

ROSILIO, C .

JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (03) :1042-1050

[3]

RESONANCE RAMAN AND INFRARED STUDIES OF LANGMUIR-BLODGETT-FILMS OF 3,3-DIMETHYL-2-[3-(3,3-DIMETHYL-1-OCTADECYL-2-INDOLINYLIDENE)-1-PROPENYL]-1-OCTADECYL-3H-INDOLIUM IODIDE [J].

FUJIMOTO, Y ;

KATAYAMA, N ;

OZAKI, Y ;

ARAKI, T ;

IRIYAMA, K .

THIN SOLID FILMS, 1992, 210 (1-2) :597-600

[4]

SUBSTRATE AND SURFACE PRESSURE DEPENDENCIES OF THE MOLECULAR-ORIENTATION AND STRUCTURE OF ARACHIDIC ACID MONOLAYER FILMS [J].

FUJIMOTO, Y ;

OZAKI, Y ;

KATO, T ;

MATSUMOTO, N ;

IRIYAMA, K .

CHEMICAL PHYSICS LETTERS, 1992, 196 (3-4) :347-352

[5]

THE CRYSTAL-STRUCTURE OF THE B'-FORM OF HEPTADECANOIC ACID [J].

GOTO, M ;

ASADA, E .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1984, 57 (04) :1145-1146

[6]

THE CRYSTAL-STRUCTURE OF THE A'-FORM OF TRIDECANOIC ACID [J].

GOTO, M ;

ASADA, E .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (08) :2111-2113

[7]

INFRARED STUDY OF ADSORBED MOLECULES ON METAL SURFACES BY REFLECTION TECHNIQUES [J].

GREENLER, RG .

JOURNAL OF CHEMICAL PHYSICS, 1966, 44 (01) :310-&

[8]

INFRARED SPECTROSCOPIC EVIDENCE FOR COEXISTENCE OF 2 MOLECULAR CONFIGURATIONS IN CRYSTALLINE FATTY-ACIDS [J].

HAYASHI, S ;

UMEMURA, J .

JOURNAL OF CHEMICAL PHYSICS, 1975, 63 (05) :1732-1740

[9]

INFRARED SPECTRA OF SINGLE CRYSTALS .1. ORTHORHOMBIC N-C24H50, MONOCLINIC N-C36H74, AND TRICLINIC N-C18H38 AND N-C20H42 [J].

HOLLAND, RF ;

NIELSEN, JR .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1962, 8 (05) :383-&

[10]

MOLECULAR AGGREGATION, ORIENTATION, AND STRUCTURE IN LANGMUIR-BLODGETT-FILMS OF 2-(4'-(ETHYLOCTADECYLAMINO)PHENYLAZO)-N-METHYLBENZOTHIAZOLIUM PERCHLORATE AND 2-(4'-(DIOCTADECYLAMINO)PHENYLAZO)-N-METHYLBENZOTHIAZOLIUM PERCHLORATE STUDIES BY INFRARED, VISIBLE ABSORPTION, AND RESONANCE RAMAN SPECTROSCOPIES [J].

KATAYAMA, N ;

FUKUI, M ;

OZAKI, Y ;

KURAMOTO, N ;

ARAKI, T ;

IRIYAMA, K .

LANGMUIR, 1991, 7 (11) :2827-2832

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