SILYLATIVE CYCLOCARBONYLATION OF ACETYLENIC BONDS CATALYZED BY RH-4(CO)(12) - AN EASY ACCESS TO BICYCLO[3.3.0]OCTENONE SKELETONS

被引：31

作者：

MATSUDA, I

ISHIBASHI, H

II, N

机构：

[1] Department of Applied Chemistry, School of Engineering, Nagoya University, Chikusa, Nagoya

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 02期

关键词：

D O I：

10.1016/0040-4039(94)02182-B

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A rhodium-catalyzed cyclopentenone annulation is found in the reaction of two moles of phenylacetylene and (t)BuMe(2)SiH under CO pressure. This type of CO incorporation is applied to the construction of bicyclo[3.3.0]octenone frameworks from 1,6-diynes.

引用

页码：241 / 244

页数：4

共 29 条

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