X-RAY STRUCTURE OF THE ALPHA-CYCLODEXTRIN FERROCENE (2-1) INCLUSION COMPOUND

被引:66
作者
ODAGAKI, Y
HIROTSU, K
HIGUCHI, T
HARADA, A
TAKAHASHI, S
机构
[1] OSAKA CITY UNIV,FAC SCI,DEPT CHEM,SUMIYOSHI KU,OSAKA 558,JAPAN
[2] OSAKA UNIV,FAC SCI,DEPT MACROMOLEC SCI,TOYONAKA,OSAKA 560,JAPAN
[3] OSAKA UNIV,INST SCI & IND RES,IBARAKI,OSAKA 567,JAPAN
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 04期
关键词
D O I
10.1039/p19900001230
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The crystal structure of the α-cyclodextrin-ferrocene (2:1) inclusion compound has been determined by an X-ray analysis which shows that the ferrocene molecule with approximate D5d symmetry is encapsulated by the dimer of the α-cyclodextrins in a tail-to-tail orientation and inclined by 42° relative to the six-fold axes of the α-cyclodextrins of the dimer.
引用
收藏
页码:1230 / 1231
页数:2
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