THE DICOBALT HEXACARBONYL(ALKYNE) MOIETY AS A STEREOCONTROL ELEMENT IN INTRAMOLECULAR FRIEDEL-CRAFTS ALKYLATIONS

被引：13

作者：

GROVE, DD ^{[1
]}

CORTE, JR ^{[1
]}

SPENCER, RP ^{[1
]}

PAULY, ME ^{[1
]}

RATH, NP ^{[1
]}

机构：

[1] UNIV MISSOURI,DEPT CHEM,ST LOUIS,MO 63121

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 01期

关键词：

D O I：

10.1039/c39940000049

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A dicobalt hexacarbonyl(alkyne) moiety is used as a stereocontrol element in Friedel-Crafts cycloalkylation reactions that deliver cis-4a-ethynyl-1,2,3,4,4a,9,10,10a-octahydrophenanthrenes exclusively.

引用

页码：49 / 50

页数：2

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