METHOXYMETHYLENE(TRIPHENYL)PHOSPHORANE FROM ALKYLLITHIUM REAGENTS

被引：14

作者：

ANDERSON, CL

SODERQUIST, JA

KABALKA, GW

机构：

[1] UNIV PUERTO RICO,DEPT CHEM,RIO PIEDRAS,PR 00931

[2] UNIV TENNESSEE,DEPT CHEM,KNOXVILLE,TN 37996

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 46期

关键词：

D O I：

10.1016/S0040-4039(00)60894-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Whereas Li(t-Bu) is an efficient base for the generation of Ph3PCHOMe, Li(n-Bu) gives both this ylide and a butylidene ylide which is consistent with a Ph2(MeOCH2)PCH(n-Pr) formulation. P-31 NMR studies and their reactions with acylsilanes are described.

引用

页码：6915 / 6918

页数：4

共 54 条

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