SYNTHESIS OF TOTALLY RIGID COVALENTLY-LINKED BIS-PORPHYRIN SYSTEMS FOR STUDYING LONG-RANGE ELECTRON-TRANSFER AND ENERGY-TRANSFER PROCESSES

被引:32
作者
ATKINSON, EJ [1 ]
OLIVER, AM [1 ]
PADDONROW, MN [1 ]
机构
[1] UNIV NEW S WALES,SCH CHEM,POB 1,KENSINGTON,NSW 2033,AUSTRALIA
关键词
D O I
10.1016/S0040-4039(00)61753-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis of novel rigid covalently linked bis-porphyrin systems, 3 - 5, and the monoporphyrin model, 6, is described. The synthetic strategy entails formation of o-phenylenediamine units, 11, and their reaction with the dioxotetraphenylchlorin, 12.
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页码:6147 / 6150
页数:4
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