Crystal structure of dicarbonyl(eta(5)-cyclopentadienyl) (triphenylphosphine)iron hexafluorophosphate, [(eta(5)-C5H5)Fe(CO)(2)(PPh(3))(+)][PF6-]

被引：8

作者：

Janik, TS ^{[1
]}

Krajkowski, LM ^{[1
]}

Churchill, MR ^{[1
]}

机构：

[1] SUNY BUFFALO,DEPT CHEM,BUFFALO,NY 14260

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1995年 / 25卷 / 11期

关键词：

cationic iron complex; iron phosphine complex;

D O I：

10.1007/BF01670330

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound crystallizes in the centrosymmetric triclinic space group P (l) over bar (No. 2) with a = 10.818(1)Angstrom b = 10.876(1)Angstrom, c 11.072(2)Angstrom, alpha = 98.74(1)degrees, beta = 98.83(1)degrees, gamma = 96.61(1)degrees, V = 1259.6(3)Angstrom(3) and Z = 2. Interatomic distances include Fe-P = 2.243(2)Angstrom, Fe-CO= 1.771(6)-1.781(5)Angstrom Fe-C(C5H5) = 2.074(6)-2.103(5)Angstrom and P-F = 1.511(6)1.571(4)Angstrom.

引用

页码：751 / 754

页数：4

共 7 条

[1] DIRECT PREPARATION OF [(H5-C5H5)FE(CO)2(H2-ALKENE)]+ COMPLEXES FROM [(H5-C5H5)FE(CO)2]2 [J].