SYNTHESIS OF A NEW RECEPTOR-BASED ON UPPER RIM FUNCTIONALIZED CALIX[5]ARENE

被引:37
作者
HAINO, T [1 ]
HARANO, T [1 ]
MATSUMURA, K [1 ]
FUKAZAWA, Y [1 ]
机构
[1] HIROSHIMA UNIV,FAC SCI,DEPT CHEM,HIGASHIHIROSHIMA 724,JAPAN
关键词
D O I
10.1016/00404-0399(50)1130A-
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new carix[5]arene possessing two benzoic acid moieties was synthesized as an artificial receptor, and its ability of binding for imidazole was investigated. The carix[5]arene forms a cone shaped cavity, in which two imidazolium ions were included. The structure of the complex with two imidazolium ions was proposed by using Monte-Carlo-AMBER* simulation in Macro Model V. 4.0.
引用
收藏
页码:5793 / 5796
页数:4
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