A CONVENIENT SYNTHESIS OF BOTH ENANTIOMERS OF SEUDENOL AND THEIR CONVERSION TO 1-METHYL-2-CYCLOHEXEN-1-OL (MCOL)

被引：16

作者：

JOHNSTON, BD

MORGAN, B

OEHLSCHLAGER, AC

RAMASWAMY, S

机构：

[1] SIMON FRASER UNIV,DEPT CHEM,BURNABY V5A 1S6,BC,CANADA

[2] PHERO TECH INC,DELTA V4C 1E9,BC,CANADA

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 05期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0957-4166(00)82123-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

PPL catalyzed transesterification of seudenol (2) in dry Et2O yielded both optically enriched enantiomers (greater-than-or-equal-to 95% ee). Epoxidation, mesylation and reductive ring opening furnished optically enriched MCOL (1).

引用

页码：377 / 380

页数：4

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