AN EFFECTIVE ACTIVATION OF O-TRIMETHYLSILYL MONOTHIOACETAL UNDER EXTREMELY MILD CONDITIONS USING A NOVEL CATALYST SYSTEM, TRIMETHYLSILYL CHLORIDE AND INDIUM(III) CHLORIDE

被引：27

作者：

MUKAIYAMA, T

OHNO, T

NISHIMURA, T

HAN, JS

KOBAYASHI, S

机构：

来源：

CHEMISTRY LETTERS | 1990年 / 12期

关键词：

D O I：

10.1246/cl.1990.2239

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel catalyst system, trimethylsilyl chloride and indium(III) chloride, effectively catalyzes the reaction of O-trimethylsilyl monothioacetals with triethylsilane and silylated carbon nucleophiles, respectively, to afford the corresponding sulfide derivatives in good to high yields.

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页码：2239 / 2242

页数：4

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