THE X2(2)PI-1/2-]X1(2)PI-3/2 ELECTRONIC-TRANSITIONS OF TELLURIUM MONOHALIDES IN THE NEAR-INFRARED

被引：14

作者：

FINK, EH ^{[1
]}

SETZER, KD ^{[1
]}

RAMSAY, DA ^{[1
]}

VERVLOET, M ^{[1
]}

机构：

[1] NATL RES COUNCIL CANADA,HERZBERG INST ASTROPHYS,OTTAWA K1A 0R6,ONTARIO,CANADA

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 177卷 / 03期

关键词：

D O I：

10.1016/0009-2614(91)85027-T

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Emission spectra of the 0-0 bands of the transitions X2 2-PI-1/2-->X1 2-PI-3/2 between the fine-structure components of the X 2-PI-i ground states of TeF, TeCl, TeBr and TeI have been observed in the near-infrared spectral region between 2.35 and 2.5-mu-m. The X2 2-PI-1/2 states of the radicals were excited by addition of halogens to the reaction system of microwave-discharged H-2 with tellurium powder in a fast-flow system. The fine-structure splittings of the X 2-PI-i ground states were found to be 4187 +/- 1 cm-1 (TeF), 4022.5 +/- 1 cm-1 (TeCl), 4067 +/- 3 cm-1 (TeBr) and 4130 +/- 10 cm-1 (TeI).

引用

页码：265 / 268

页数：4

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