THE INFLUENCE OF SUBSTITUENTS ON THE LUMINESCENCE PROPERTIES OF THE EU(III) AND TB(III) CHELATES OF 4-(PHENYLETHYNYL)PYRIDINE DERIVATIVES

被引：9

作者：

TAKALO, H ^{[1
]}

HANNINEN, E ^{[1
]}

KANKARE, J ^{[1
]}

机构：

[1] UNIV TURKU,DEPT CHEM,SF-20500 TURKU,FINLAND

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1995年 / 225卷 / 1-2期

关键词：

LUMINESCENCE; CHELATES; EUROPIUM; TERBIUM; SUBSTITUENTS;

D O I：

10.1016/0925-8388(94)07097-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

42 differently substituted 2,2',2 '',2'''-{[4-(phenylethynyl)pyridine-2,6-diyl]bis(methylenenitrilo)}tetrakis(acetic acids) (1-42) were synthesized with the purpose of studying the influence of substituents on the luminescence properties of the Eu(III) and Tb(III) chelates. With the Eu(III) ion, all derivatives (amides, ketones, esters, acids, ethers, halides and nitriles), with the exception of amines, gave a strong emission with suitable excitation wavelengths while, with the Tb(III) ion, only meta-substituted carbonyl derivatives had moderate luminescence properties.

引用

收藏

页码：511 / 514

页数：4

相关论文

共 11 条

[1] PREPARATION OF NEW COMPLEXING AGENTS CONTAINING A HIGHLY CONJUGATED ETHYNYLATED PYRIDINE SUBUNIT [J].

HANNINEN, E ;

TAKALO, H ;

KANKARE, J .

ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1988, 42 (09) :614-619

[2]

HEMMILA I, 1994, BIOANALYTICAL APPLIC

[3] NEW 2,2'-BIPYRIDINE DERIVATIVES AND THEIR LUMINESCENCE PROPERTIES WITH EUROPIUM(III) AND TERBIUM(III) IONS [J].

MUKKALA, VM ;

KANKARE, JJ .

HELVETICA CHIMICA ACTA, 1992, 75 (05) :1578-1592

[4] INFLUENCE OF CHELATING GROUPS ON THE LUMINESCENCE PROPERTIES OF EUROPIUM(III) AND TERBIUM(III) CHELATES IN THE 2,2'-BIPYRIDINE SERIES [J].

MUKKALA, VM ;

KWIATKOWSKI, M ;

KANKARE, J ;

TAKALO, H .

HELVETICA CHIMICA ACTA, 1993, 76 (02) :893-899

[5] NEW HETEROAROMATIC COMPLEXING AGENTS AND LUMINESCENCE OF THEIR EUROPIUM(III) AND TERBIUM(III) CHELATES [J].

MUKKALA, VM ;

SUND, C ;

KWIATKOWSKI, M ;

PASANEN, P ;

HOGBERG, M ;

KANKARE, J ;

TAKALO, H .

HELVETICA CHIMICA ACTA, 1992, 75 (05) :1621-1632

[6] DEVELOPMENT OF LUMINESCENT EUROPIUM(III) AND TERBIUM(III) CHELATES OF 2,2'/6',2''-TERPYRIDINE DERIVATIVES FOR PROTEIN LABELING [J].

MUKKALA, VM ;

HELENIUS, M ;

HEMMILA, I ;

KANKARE, J ;

TAKALO, H .

HELVETICA CHIMICA ACTA, 1993, 76 (03) :1361-1378

[7] TIME-RESOLVED FLUORESCENCE IMAGING OF EUROPIUM CHELATE LABEL IN IMMUNOHISTOCHEMISTRY AND INSITU HYBRIDIZATION [J].

SEVEUS, L ;

VAISALA, M ;

SYRJANEN, S ;

SANDBERG, M ;

KUUSISTO, A ;

HARJU, R ;

SALO, J ;

HEMMILA, I ;

KOJOLA, H ;

SOINI, E .

CYTOMETRY, 1992, 13 (04) :329-338

[8] SYNTHESIS OF EUROPIUM(III) CHELATES SUITABLE FOR LABELING OF BIOACTIVE MOLECULES [J].

TAKALO, H ;

MUKKALA, VM ;

MIKOLA, H ;

LIITTI, P ;

HEMMILA, I .

BIOCONJUGATE CHEMISTRY, 1994, 5 (03) :278-282

[9] SYNTHESIS OF 4-(PHENYLETHYNYL)-2,6-BIS[N,N-BIS-(CARBOXYMETHYL)AMINOMETHYL]PYRIDINE [J].

TAKALO, H ;

PASANEN, P ;

KANKARE, J .

ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1988, 42 (06) :373-377

[10] LUMINESCENCE OF EUROPIUM(III) CHELATES WITH 4-(ARYLETHYNYL)PYRIDINES AS LIGANDS [J].

TAKALO, H .

HELVETICA CHIMICA ACTA, 1993, 76 (02) :877-883