LITHIUM HYDRIDE CONTAINING COMPLEX REDUCING AGENT - A NEW AND SIMPLE ACTIVATION OF COMMERCIAL LITHIUM HYDRIDE

被引：22

作者：

FORT, Y

机构：

[1] Laboratoire de Chimie Organique I, associé au CNRS, Faculté des Sciences, 54506 Vandoeuvre les Nancy

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 34期

关键词：

D O I：

10.1016/0040-4039(95)01240-I

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Commercially available lithium hydride, an essentially inert metal hydride, can be activated as a hydride source by in situ generated lithium alkoxide in the presence of a nickel salt. The obtained new reagent exhibited reducing properties versus alkyl or aryl halides, ketones, ethylenic or sulfurated compounds as well as coupling properties versus aryl halides when prepared in the presence of a ligand.

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页码：6051 / 6054

页数：4

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