MECHANISM OF DIAMOND GROWTH IN THE PRESENCE OF ATOMIC-HYDROGEN

被引：35

作者：

DEAK, P ^{[1
]}

GIBER, J ^{[1
]}

OECHSNER, H ^{[1
]}

机构：

[1] UNIV KAISERSLAUTERN,FACHBEREICH PHYS,W-6750 KAISERSLAUTERN,GERMANY

来源：

SURFACE SCIENCE | 1991年 / 250卷 / 1-3期

关键词：

D O I：

10.1016/0039-6028(91)90732-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The heat of reactions between methyl radicals, atomic hydrogen and a two-dimensionally periodic (111) diamond slab has been calculated using a semi-empirical quantum chemical approach. A sequence of energetically favorable stable surface complexes is established leading to diamond-like growth.

引用

页码：287 / 290

页数：4

共 14 条

[1] LOW-PRESSURE, METASTABLE GROWTH OF DIAMOND AND DIAMONDLIKE PHASES [J].

ANGUS, JC ;

HAYMAN, CC .

SCIENCE, 1988, 241 (4868) :913-921

[2] GROUND-STATES OF MOLECULES .25. MINDO-3 - IMPROVED VERSION OF MINDO SEMIEMPIRICAL SCF-MO METHOD [J].

BINGHAM, RC ;

DEWAR, MJS ;

LO, DH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1285-1293

[3] STATE AND MOTION OF HYDROGEN IN CRYSTALLINE SILICON [J].

DEAK, P ;

SNYDER, LC ;

CORBETT, JW .

PHYSICAL REVIEW B, 1988, 37 (12) :6887-6892

[4] PRELIMINARY CALCULATIONS CONFIRMING THAT ANOMALOUS MUONIUM IN DIAMOND AND SILICON IS BOND-CENTERED INTERSTITIAL MUONIUM [J].

ESTLE, TL ;

ESTREICHER, S ;

MARYNICK, DS .

HYPERFINE INTERACTIONS, 1986, 32 (1-4) :637-639

[5] GROWTH-MECHANISM OF VAPOR-DEPOSITED DIAMOND [J].

FRENKLACH, M ;

SPEAR, KE .

JOURNAL OF MATERIALS RESEARCH, 1988, 3 (01) :133-140

[6] ENERGETICS OF ACETYLENE-ADDITION MECHANISM OF DIAMOND GROWTH [J].

HUANG, D ;

FRENKLACH, M ;

MARONCELLI, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (22) :6379-6381

[7] RAPID SINGLE CRYSTALLINE DIAMOND GROWTH BY ACETYLENE OXYGEN FLAME DEPOSITION [J].

JANSSEN, G ;

VANENCKEVORT, WJP ;

SCHAMINEE, JJD ;

VOLLENBERG, W ;

GILING, LJ ;

SEAL, M .

JOURNAL OF CRYSTAL GROWTH, 1990, 104 (03) :752-757

[8] THE GROWTH-MECHANISM OF DIAMOND CRYSTALS IN ACETYLENE FLAMES [J].

MATSUI, Y ;

YABE, H ;

HIROSE, Y .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1990, 29 (08) :1552-1560

[9]

OECHSNER H, 1990, EINIGE MOGLICHKEITEN

[10] THE DIAMOND SURFACE - ATOMIC AND ELECTRONIC-STRUCTURE [J].

PATE, BB .

SURFACE SCIENCE, 1986, 165 (01) :83-142

← 1 2 →