FEMTOCHEMISTRY - RECENT ADVANCES AND EXTENSION TO HIGH-PRESSURES

被引:44
作者
ZEWAIL, AH
DANTUS, M
BOWMAN, RM
MOKHTARI, A
机构
[1] Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena
基金
美国国家科学基金会;
关键词
D O I
10.1016/1010-6030(92)85061-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recent advances made in laser femtochemistry are presented. Extensions to the high pressure regime (and liquids) are demonstrated, using as an example, the classic case of iodine dissociation and recombination. In femtochemistry the motion of the nuclei is followed with femtosecond time resolution and the dynamics are studied during the course of the reaction - the transition states. The examples given here draw on increasing complexity - from elementary chemical reactions under isolated molecular conditions to more complex reactions with many degrees of freedom, and move toward the condensed phase limit.
引用
收藏
页码:301 / 319
页数:19
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