CATALYZED ISOMERIZATION OF SIMPLE RADICAL CATIONS IN THE GAS-PHASE

被引：74

作者：

AUDIER, HE

LEBLANC, D

MOURGUES, P

MCMAHON, TB

HAMMERUM, S

机构：

[1] UNIV WATERLOO,DEPT CHEM,WATERLOO N2L 3G1,ON,CANADA

[2] UNIV COPENHAGEN,HC ORSTED INST,DEPT CHEM,DK-2100 COPENHAGEN 0,DENMARK

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 20期

关键词：

D O I：

10.1039/c39940002329

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Interaction with polar neutral molecules can cause alpha-distonic radical cations and conventional molecular ions to interconvert in the gas phase, in spite of substantial energy barriers for the unassisted isomerization; the interconversion is particularly facile when the proton affinity of the neutral molecule is close to that of the deprotonated radical cation.

引用

页码：2329 / 2330

页数：2

共 15 条

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