SYNTHESIS AND STRUCTURE OF A DI-TANTALUM(IV) HEXAHYDRIDE COMPOUND CONTAINING ANCILLARY AMIDO LIGATION

被引：30

作者：

PROFILET, RD ^{[1
]}

FANWICK, PE ^{[1
]}

ROTHWELL, IP ^{[1
]}

机构：

[1] DEPT CHEM,1393 BROWN BLDG,W LAFAYETTE,IN 47907

来源：

POLYHEDRON | 1992年 / 11卷 / 12期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0277-5387(00)83151-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrogenation of the alkylidyne bridged dimer [(cb)2Ta(mu-CSiMe3)2Ta(cb)2] (cbH = 9H-carbazole) in the presence of PMe2Ph leads to the green hexahydride compound [(cb)(PMe2Ph)2(H)4Ta(H)(PMe2Ph)2(cb)] which contains a Ta-Ta distance of 2.5359(4) angstrom and Ta-N (carbazole) distance of 2.184(4) angstrom.

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页码：1559 / 1561

页数：3

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