APPLICATION OF F-19 NMR-SPECTROSCOPY TO THE STUDY OF EQUILIBRIUM DYNAMICS OF URANYL(2+)-FLUORIDE COMPLEXES

被引：12

作者：

SZABO, Z ^{[1
]}

GLASER, J ^{[1
]}

机构：

[1] ROYAL INST TECHNOL,DEPT CHEM INORGAN CHEM,S-10044 STOCKHOLM,SWEDEN

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1995年 / 33卷 / 01期

关键词：

NMR; F-19; MAGNETIZATION TRANSFER; 2D-EXSY; URANYL(2+)-FLUORIDE COMPLEXES; LIGAND EXCHANGE;

D O I：

10.1002/mrc.1260330106

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One- and two-dimensional magnetization-transfer F-19 NMR methods were applied in a quantitative study of the fluoride exchange for uranyl(2+)-fluoride complexes in aqueous solution. The applicability of these techniques and the classical lineshape analysis is discussed, and the quality of the results (rate constants and relaxation rates) obtained by the three methods is compared.

引用

页码：20 / 26

页数：7

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