THE PHOTO-ISOMERIZATION OF CIS-AZOBENZENE - A CHANNEL ELECTRODE STUDY

被引：19

作者：

COMPTON, RG

WELLINGTON, RG

BETHELL, D

LEDERER, P

OHARE, DM

机构：

[1] UNIV LIVERPOOL,DEPT CHEM,LIVERPOOL L69 3BX,ENGLAND

[2] UNIV OXFORD,INORGAN CHEM LAB,OXFORD OX1 3QR,ENGLAND

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1992年 / 322卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(92)80075-F

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The photo-isomerisation of cis-azobenzene by light of wavelength 432 nm has been investigated by channel electrode voltammetry. In a lithium ethoxide/ethanol medium cis-azobenzene was found to be reduced at a more positive potential (ca. 120 mV) than the trans isomer in the dark at a gold electrode. Quantitative waveshape measurements, with the electrode illuminated, of current-voltage curves for the reduction of the cis isomer as a function of the rate of mass transport, reveal the partial conversion of cis to trans and enable the quantum yield for the cis to trans isomerisation to be found as PHI = 0.21.

引用

页码：183 / 190

页数：8

共 26 条

[1] ALTERNATING AND DIRECT CURRENT POLAROGRAPHY OF AZOBENZENE IN INDIFFERENT ELECTROLYTE IN DIMETHYLFORMAMIDE
AYLWARD, GH
GARNETT, JL
SHARP, JH
[J]. ANALYTICAL CHEMISTRY, 1967, 39 (04) : 457 - &
[2] BOTO KG, 1965, AUST J CHEM, V17, P1085
[3] VOLTAMMETRIC BEHAVIOR OF AZOXYBENZENE AZOBENZENE AND HYDRAZOBENZENE AT GRAPHITE ELECTRODE
CHUANG, L
FRIED, I
ELVING, PJ
[J]. ANALYTICAL CHEMISTRY, 1965, 37 (12) : 1528 - &
[4] STRUCTURES OF CONJUGATE ACIDS OF CIS- AND TRANS-AZOBENZENES
COLLINS, JH
JAFFE, HH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (24) : 4708 - &
[5] DOUBLE CHANNEL ELECTRODES AND THE MEASUREMENT OF HETEROGENEOUS REACTION-RATES AT THE SOLID LIQUID INTERFACE
COMPTON, RG
STEARN, GM
UNWIN, PR
BARWISE, AJ
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1988, 18 (04) : 657 - 665
[6] PHOTOELECTROCHEMICAL ELECTRON-SPIN RESONANCE .2. THE REDUCTION OF CRYSTAL VIOLET IN ACETONITRILE
COMPTON, RG
COLES, BA
STEARN, GM
WALLER, AM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1988, 84 : 2357 - 2367
[7] PHOTOCHEMICAL EXPULSION OF IODIDE FROM THE 1-IODOANTHRAQUINONE RADICAL-ANION
COMPTON, RG
FISHER, AC
WELLINGTON, RG
BETHELL, D
LEDERER, P
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (12) : 4749 - 4752
[8] PHOTOELECTROCHEMICAL ELECTRON-SPIN RESONANCE .3. THE REDUCTION OF FLUORESCEIN - A PHOTO-DISP2 REACTION
COMPTON, RG
COLES, BA
PILKINGTON, MBG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1988, 84 : 4347 - 4357
[9] PHOTOELECTROCHEMICAL ELECTRON-SPIN-RESONANCE .4. THE PHOTO-ECE REACTION AND THE REDUCTION OF 1-HALOGENOANTHRAQUINONES
COMPTON, RG
COLES, BA
PILKINGTON, MBG
BETHELL, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (04): : 663 - 670
[10] MASS-TRANSPORT IN CHANNEL ELECTRODES - THE APPLICATION OF THE BACKWARDS IMPLICIT METHOD TO ELECTRODE-REACTIONS (EC, ECE AND DISP) INVOLVING COUPLED HOMOGENEOUS KINETICS
COMPTON, RG
PILKINGTON, MBG
STEARN, GM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1988, 84 : 2155 - 2171

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