A REVISED MECHANISM FOR CHEMOSELECTIVE REDUCTION OF ESTERS WITH BORANE-DIMETHYL SULFIDE COMPLEX AND CATALYTIC SODIUM TETRAHYDROBORATE DIRECTED BY ADJACENT HYDROXYL GROUP

被引：130

作者：

SAITO, S

ISHIKAWA, T

KURODA, A

KOGA, K

MORIWAKE, T

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Okayama University, Tsushima, 700, Okayama, Japan

来源：

TETRAHEDRON | 1992年 / 48卷 / 20期

关键词：

D O I：

10.1016/S0040-4020(01)92187-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The plausible mechanism for the reduction of the ester groups with a strong preference for one located alpha to the hydroxyl groups of (S)-malates and (R,R)-tartrate-based derivatives has been proposed together with some results with regard to its applications to the syntheses of chiral synthons.

引用

页码：4067 / 4086

页数：20

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