STATIC VISCOSITY OF SUPERCOOLED 3-BROMOPENTANE IN MIXTURES WITH 3-METHYLPENTANE

被引：10

作者：

BARANEK, M ^{[1
]}

BRESLIN, M ^{[1
]}

BERBERIAN, JG ^{[1
]}

机构：

[1] ST JOSEPHS UNIV,DEPT CHEM,PHILADELPHIA,PA 19131

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1994年 / 172卷 / pt 1期

关键词：

D O I：

10.1016/0022-3093(94)90439-1

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Static viscosity measurements of two mixtures of 3-bromopentane in 5-methylpentane are presented in the temperature range from 94 to 112 K and over a range of viscosities from 3 x 10(7) to 280 Pas. The data are fitted to the Vogel-Fulcher-Tamman equation. Estimates of the glass transition temperatures for these mixtures based on the reference viscosity of 1 x 10(12) Pas 90.1 and 98.8 K for 0.500 mole fraction and 0.750 mole fraction of 3-bromopentane in 3-methylpentane, respectively. Additionally, viscosity measurements on pure 3-methylpentane, previously reported, have been extended to higher temperatures. These viscosity values and those measured in this laboratory on 3-bromopentane, along with estimates of their glass transition temperatures, are also presented for comparison purposes.

引用

页码：223 / 228

页数：6

共 15 条

[1] ON TEMPERATURE DEPENDENCE OF COOPERATIVE RELAXATION PROPERTIES IN GLASS-FORMING LIQUIDS [J].