A DONOR CAGE WITH 2 TETRATHIAFULVALENE UNITS

被引：46

作者：

ADAM, M ^{[1
]}

ENKELMANN, V ^{[1
]}

RADER, HJ ^{[1
]}

ROHRICH, J ^{[1
]}

MULLEN, K ^{[1
]}

机构：

[1] MAX PLANCK INST POLYMER RES,ACKRMANNWEG 10,W-6500 MAINZ,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 03期

关键词：

D O I：

10.1002/anie.199203091

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclophane 1 with four donor units (two tetrathiafulvalene (TTF) and two hydroquinone units) can be prepared by anodic oxidation of a strained cyclic "monomer" containing both of these donor components. Although in the solid state the TTF units in 1 are bent towards the cavity, making it too small for guest molecules, force-field calculations show that in solution conformations with a sufficiently large cavity may arise. R = propyl, butyl.

引用

页码：309 / 310

页数：2

共 7 条

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