SHOCK-TUBE AND MODELING STUDY OF PROPENE PYROLYSIS

被引：67

作者：

HIDAKA, Y ^{[1
]}

NAKAMURA, T ^{[1
]}

TANAKA, H ^{[1
]}

JINNO, A ^{[1
]}

KAWANO, H ^{[1
]}

HIGASHIHARA, T ^{[1
]}

机构：

[1] MATSUE COLL TECHNOL,MATSUE 690,JAPAN

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1992年 / 24卷 / 09期

关键词：

D O I：

10.1002/kin.550240902

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The thermal decomposition of propene behind reflected shock waves with 1200 < T5 < 1800 K and 1.6 x 10(-5) < rho-5 < 2.7 x 10(-5) mol/cm3 was studied by IR laser kinetic absorption spectroscopy and gas-chromatographic analysis of reaction products. The present data together with earlier shock tube data were satisfactorily modeled with a 51-reaction mechanism. As the initial step of the reaction, three channels, C3H6 = CH3 + C2H3 (1), C3H6 = H + AC3H5 (2), and C3H6 = CH4 + C2H2 (3), were necessary to interpret all the experimental data.

引用

页码：761 / 780

页数：20

共 48 条

[1] SINGLET METHYLENE KINETICS - DIRECT MEASUREMENTS OF REMOVAL RATES OF A1A1 AND B1B1 CH2 AND CD2
ASHFOLD, MNR
FULLSTONE, MA
HANCOCK, G
KETLEY, GW
[J]. CHEMICAL PHYSICS, 1981, 55 (02) : 245 - 257
[2] KINETICS OF THE REACTION - 2C2H4-]C2H5+C2H3. HEAT OF FORMATION OF THE VINYL RADICAL
AYRANCI, G
BACK, MH
[J]. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1983, 15 (01) : 83 - 104
[3] Back M. H, 1970, INT J CHEM KINET, V2, P409
[4] RATE CONSTANTS FOR THE ADDITION OF METHYL RADICALS TO PROPENE
BALDWIN, RR
KEEN, A
WALKER, RW
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1987, 83 : 759 - 766
[5] MECHANISMS FOR SOME HIGH-TEMPERATURE GAS-PHASE REACTIONS OF ETHYLENE ACETYLENE AND BUTADIENE
BENSON, SW
HAUGEN, GR
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (06) : 1735 - &
[6] BOHLAND T, 1985, BER BUNSEN PHYS CHEM, V89, P1013, DOI 10.1002/bbpc.19850890917
[7] BRAUNUNKHOFF M, IN PRESS 17TH S INT
[8] CRACKING OF PROPYLENE IN A SHOCK-TUBE
BURCAT, A
[J]. FUEL, 1975, 54 (02) : 87 - 93
[9] REACTION OF HYDROGEN-ATOMS WITH ETHANE
CAMILLERI, P
MARSHALL, RM
PURNELL, JH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1974, 70 (08): : 1434 - 1444
[10] CATHONNET M, 1981, 18TH S INT COMB PITT, P903

← 1 2 3 4 5 →