ELECTRONIC CONDUCTIVITY OF POLYCRYSTALLINE NA-BETA-ALUMINA AT HIGH-TEMPERATURE

被引：26

作者：

NAFE, H ^{[1
]}

STEINBRUCK, M ^{[1
]}

机构：

[1] KERNFORSCHUNGSZENTRUM KARLSRUHE,INST REAKTORSICHERHEIT,D-76021 KARLSRUHE,GERMANY

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1994年 / 141卷 / 10期

关键词：

alumina; electrical conductivity measurement; electrochemical sensors; sodium; solid electrolytes cells (electric); thermoelectric conversion;

D O I：

10.1149/1.2059215

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

From defect chemical considerations the sodium potential dependencies of the partial electronic conductivities of Na-beta-alumina are derived. As a result, relationships for the ionic transference number, the open-circuit voltage of a galvanic cell, the steady-state ionic current and the sodium potential profile across the electrolyte can be solved for. These relationships serve as a theoretical basis to determine and discuss the role of the partial electronic conductivities under defined operating conditions of the electrolyte.

引用

页码：2779 / 2783

页数：5

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