EXTRACTION EQUILIBRIA OF GALLIUM (III) WITH LIX-54 FROM HYDROCHLORIC-ACID SOLUTIONS

被引：6

作者：

GUTIERREZ, B

PAZOS, C

COCA, J

机构：

[1] Department of Chemical Engineering, University of Oviedo

来源：

SOLVENT EXTRACTION AND ION EXCHANGE | 1993年 / 11卷 / 05期

关键词：

D O I：

10.1080/07366299308918185

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Extraction equilibrium data of gallium (III) from hydrochloric acid solutions with LIX 54 dissolved in kerosene were measured at 20 and 60-degrees-C. The extraction mechanism, as shown by lineal plots, involves the formation of Ga(LIX 54)3 complexes. Extraction kinetics are much faster at higher temperatures. Gallium stripping from loaded extracts can be carried out by contacting these with aqueous solutions containing hydrochloric acid in a concentration range of 0.21-1.20 mol-g/dm3.

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页码：769 / 782

页数：14

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